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THE SPECTRO-PAEDIA

click on any item in the list for its wikipedia entry if available.


absorbance
adsorption
Atomization
bandwidth
Beamsplitters
bioluminescence
chemiluminescence
chromatography
electroluminescence
electromagnetic
emission
Emissivity
Fluorescence
luminescence
Michelson
monochromators
photo-multiplier
Phosphorescence
photodiodes
photoelectric
photoluminescence
Rayleigh
Raman
spectrofluorometer
spectrometer
spectrophotometer
Spectrum
Transmittance
ultraviolet
Visible
wavelength
Wavenumber
UV Light
Beer's Law
Diode Array
Deuterium Discharge Lamp
Low Pressure Zinc Discharge Lamp
High Pressure Mercury Discharge Lamp
Low Pressure Cadmium Lamp
Tungsten Halogen Lamp
Lens and Window Material in Spectrometers
Cuvettes
Luminescence
Photoluminescence
Fluorescence
Phosphorescence
Bioluminescence
Radioluminescence
Electroluminescence
Fluorescence Reagents
Spectrum
Diffraction Grating
Interferogram
Fourier Transform IR Spectrometer
FT-IR
Halide Disks
Mull Samples
Film Samples for IR Spectroscopy
Light Pipes
Attenuated Total Reflectance Spectroscopy
Multiple Internal Reflectance
External Reflectance
Specular Reflectance
Diffuse Reflectance
Photoacoustic Spectroscopy
Beam Splitter
Raman Scattering
Rayleigh Scattering
Raman Spectroscopy
Atomic Spectroscopy
Atomic Emission Spectroscopy
Atomic Absorption Spectroscopy
The Inductively Coupled Plasma Torch
The Helium Plasma Torch
Emission Spectrometer
Atomic Absorption Spectrometry
Flame Atomic Absorption Spectrometer
Flame AA
Hollow Cathode Lamp
Electrothermal Atomization
Graphite Furnace
L’vov Platform
Electron Paramagnetic Resonance
Zeeman Effect
Continuous Wave
Electron Paramagnetic Resonance
Pulsed EPR
Electron Spin Echo
Multple Resonance Spectroscopy
Magnetic Resonance Spectroscopy
NMR
Precessing
Nucleus Spin Decoupling in NMR
Superconducting Magnets
NMR Microcells
Electron Impact Ionisation
Chemical Ionization
Inductively Coupled Plasma Ionization
Secondary Ion Mass Spectrometry
Fast Atom Bombardment
Plasma Desorption Mass Spectrometry
Laser Desorption Mass Spectrometry
Matrix Assisted Desorption mass Spectrometry
Field Desorption Ionization
Thermospray Ionization
Electrospray Ionization
Atmospheric Pressure Ionization
Particle Beam Interface
Permeable Membrane Interface
Sector Mass Spectrometer
Quadrupole Mass Spectrometer
Ion Trap Mass Spectrometer
Time of Flight Mass Spectrometer
Optical RotationCircular Dichroism
Circularly Polarized Light
Verdet Constant
Faraday Effect
 

The Simple Grating Infrared Spectrometer

A diagram of the grating IR spectrometer is shown in figure 9.

Figure 9. The Simple Grating IR Spectrometer

Light from the IR source is reflected from a mirror, through the reference cell, through an attenuator system and onto a second mirror, By imposing a simple device in the path of the reference light beam that removes a continuous. but controllable, fraction of the light allows the reference beam to be attenuated. The attenuator can take the form of a comb, the teeth of which are cut so that the amount of light attenuated is linearly related to the lateral movement of the comb through the beam. After passing through the attenuator to the second mirror, the attenuated light passes through a chopper. The chopper has reflecting and transmitting surfaces and, thus, alternately allows light to pass from the reference cell to the grating and then light from the sample cell to the grating. At the grating light of a specific wavelength is selected to pass to the IR detector.

As a consequence, the chopper arranges for the sensor to alternately receive light that has been transmitted through the cell, and light that has passed through the attenuator. A servomechanism controls the attenuator that is actuated by the output from the sensor and adjusts the light transmission until both beams have the same intensity. The amount of light that is absorbed is indicated by the position of the attenuator. In other words, the amount of light, of a particular wavelength, which is absorbed by the sample, is measured by attenuating the reference beam until its intensity is equivalent to that of the beam transmitted through the sample. The resolution is controlled by the width of the slit, which is adjustable. In the older versions of this type of IR spectrometer, an analogue plotter, mechanically associated with the attenuator, recorded the Spectrum. More modern techniques acquire the signals from the attenuator and grating position by a compute and produce a Spectrum relating absorbance to wavelength (frequency, or wave number).

 

About the Author
RAYMOND PETER WILLIAM SCOTT was born on June 20 1924 in Erith, Kent, UK. He studied at the University of London, obtaining his B.Sc. degree in 1946 and his D.Sc. degree in 1960. After spending more than a decade at Benzole Producers, Ltd. Where he became head of the Physical Chemistry Laboratory, he moved to Unilever Research Laboratories as Manager of their Physical Chemistry department. In 1969 he became Director of Physical Chemistry at Hoffmann-La Roche, Nutley, NJ, U.S.A. and subsequently accepted the position of Director of the Applied Research Department at the Perkin-Elmer Corporation, Norwalk, CT, U.S.A.
In 1986 he became an independent consultant and was appointed Visiting Professor at Georgetown
University, Washington, DC, U.S.A. and at Berkbeck College of the University of London; in 1986 he retired but continues to write technical books dealing with various aspects of physical chemistry and physical chemical techniques. Dr. Scott has authored or co-authored over 200 peer reviewed scientific papers and authored, co-authored or edited over thirty books on various aspects of physical and analytical chemistry. Dr. Scott was a founding member of the British chromatography Society and received the American Chemical society Award in chromatography (1977), the M. S. Tswett chromatography Medal (1978), the Tswett chromatography Medal U.S.S.R., (1979), the A. J. P. Martin chromatography Award (1982) and the Royal Society of Chemistry Award in Analysis and Instrumentation (1988).
Dr. Scott’s activities in gas chromatography started at the inception of the technique, inventing the Heat of Combustion Detector (the precursor of the Flame Ionization Detector), pioneered work on high sensitivity detectors, high efficiency columns and presented fundamental treatments of the relationship between the theory and practice of the technique. He established the viability of the moving bed continuous preparative gas chromatography, examined both theoretically and experimentally those factors that controlled dispersion in packed beds and helped establish the gas chromatograph as a process monitoring instrument. Dr. Scott took and active part in the renaissance of liquid chromatography, was involved in the development of high performance liquid chromatography and invented the wire transport detector. He invented the liquid chromatography mass spectrometry transport interface, introduced micro-bore liquid chromatography columns and used them to provide columns of 750,000 theoretical plates and liquid chromatography separations in less than a second. Dr. Scott has always been a “hands-on” scientist with a remarkable record of accomplishments in chromatography ranging from hardware design to the development of fundamental theory. He has never shied away from questioning “conventional wisdom” and his original approach to problems has often produced significant breakthroughs.

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